Laser Ablative Structural Modification of Poly(ethylene-alt-maleic anhydride)

(2003) Laser Ablative Structural Modification of Poly(ethylene-alt-maleic anhydride). Chemistry of Materials, 15 (20). pp. 3887-3893.

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Abstract

Pulsed IR laser ablation of poly(ethylene-alt-maleic anhydride) results in the deposition of polymeric films possessing the same ratio of anhydride and -CH2- groups and represents a very rare example of laser ablative deposition of polymeric films that are structurally identical to the ablated polymer. This process differs from the conventional thermolysis of poly(ethylene-alt-maleic anhydride) that is controlled by expulsion of CO2 and CO and yields a nonpolar polymeric residue. The IR laser ablation of poly(ethylene-alt-maleic anhydride) in sodium metasilicate affords deposition of polymeric films containing carboxylate (-CO2-) groups. This process is the first example of reactive ablation in which the deposited polymeric film incorporates constituents of two different species exposed to laser radiation.

Item Type: Article
Subjects: Electrical
Department: College of Engineering and Physics > Electrical Engineering
Depositing User: ANKAR (g200603940) (g200603940)
Date Deposited: 23 Mar 2008 11:49
Last Modified: 01 Nov 2019 13:24
URI: https://eprints.kfupm.edu.sa/id/eprint/607