Masoudi, Husain M. (2003) Laser Ablative Structural Modification of Poly(ethylene-alt-maleic anhydride). Chemistry of Materials, 15 (20). pp. 3887-3893.
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Pulsed IR laser ablation of poly(ethylene-alt-maleic anhydride) results in the deposition of polymeric films possessing the same ratio of anhydride and -CH2- groups and represents a very rare example of laser ablative deposition of polymeric films that are structurally identical to the ablated polymer. This process differs from the conventional thermolysis of poly(ethylene-alt-maleic anhydride) that is controlled by expulsion of CO2 and CO and yields a nonpolar polymeric residue. The IR laser ablation of poly(ethylene-alt-maleic anhydride) in sodium metasilicate affords deposition of polymeric films containing carboxylate (-CO2-) groups. This process is the first example of reactive ablation in which the deposited polymeric film incorporates constituents of two different species exposed to laser radiation.
|Date:||12 September 2003|
|Divisions:||College Of Engineering Sciences > Electrical Engineering Dept|
|Creators:||Masoudi, Husain M.|
|Deposited By:||ANKAR (g200603940) (g200603940)|
|Deposited On:||23 Mar 2008 14:49|
|Last Modified:||12 Apr 2011 13:06|
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